Preparation and properties of ferrocenyl bimetallic compounds for non-linear optics

doi:10.1016/S0020-1693(98)00134-0

Inorganica Chimica Acta

Volume 279, Issue 2, 1 October 1998, Pages 243-248

https://doi.org/10.1016/S0020-1693(98)00134-0 Get rights and content

Abstract

Ferrocenylbimetallic compounds of the form [CpFeC₅H₄CHCHpyM(CO)_n](M(CO)_nMn(CO)₅ ⁺ (4),Re(CO)₅⁺ (5), W(CO)₅ (6), Cr(CO)₅ (7), and Fe(CO)₄ (8)) have been synthesized by the ligation of the dangling pyridine to the metal carbonyl fragments, and their quadratic hyperpolarizabilities were determined using the hyper-Rayleigh scattering method. Manganese and rhenium carbonyl compounds showed considerable solvatochromism and have high hyperpolarizabilities.

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NotePreparation and properties of ferrocenyl bimetallic compounds for non-linear optics

Abstract

J. Organomet. Chem.

J. Inorg. Chim. Acta

Polyhedron

J. Organomet. Chem.

J. Organomet. Chem.

Inorg. Chim. Acta

Chem. Phys.

J. Am. Chem. Soc.

J. Organomet. Chem.

Organometallics

Inorg. Chem.

Organometallics

Nature (London)

J. Phys. Chem.

Mol. Cryst. Liq. Cryst.

Organometallics

Chem. Mater.

Angew. Chem., Int. Ed. Engl.

Appl. Organomet. Chem.

Note
Preparation and properties of ferrocenyl bimetallic compounds for non-linear optics