Issue 21, 2004
From the journal:

Dalton Transactions

Synthesis and magnetic behavior of the tetrahedral cage complex [(cyclen)4V4(CN)6]6+

In Su Leea  and  Jeffrey R. Long*a  

* Corresponding authors

a Department of Chemistry, University of California, Berkeley, California, USA
E-mail: jlong@cchem.berkeley.edu

Abstract

Reaction of [(cyclen)V(CF3SO3)2](CF3SO3) with 4 equiv. of Et4N(CN) in DMF generates the seven-coordinate complex [(cyclen)V(CN)3], while a reaction employing just 1.5 equiv. produces a tetrahedral cage complex, [(cyclen)4V4(CN)6]6+, in which antiferromagnetic coupling leads to an S = 0 ground state.

Graphical abstract: Synthesis and magnetic behavior of the tetrahedral cage complex [(cyclen)4V4(CN)6]6+

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Article information

DOI
https://doi.org/10.1039/B412804D
Article type
Communication
Submitted
19 Aug 2004
Accepted
22 Sep 2004
First published
01 Oct 2004

Dalton Trans., 2004, 3434-3436

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Synthesis and magnetic behavior of the tetrahedral cage complex [(cyclen)4V4(CN)6]6+

I. S. Lee and J. R. Long, Dalton Trans., 2004, 3434 DOI: 10.1039/B412804D

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