Issue 8, 2004

A chiral molecular bowl containing three ferrocenes: synthesis and its efficiency in an optical resolution of 1,1′-bi-2-naphthol

Abstract

Condensation reaction of 1,1′-ferrocenedicarboxaldehyde with (1R,2R)-1,2-diaminocyclohexane affords a novel bowl-shaped macrocycle with a chiral concave cavity which exhibits a remarkable ability as a host material for the enantioselective enclathration of 1,1′-bi-2-naphthol.

Graphical abstract: A chiral molecular bowl containing three ferrocenes: synthesis and its efficiency in an optical resolution of 1,1′-bi-2-naphthol

Supplementary files

Article information

Article type
Communication
Submitted
18 Dec 2003
Accepted
27 Feb 2004
First published
19 Mar 2004

Chem. Commun., 2004, 936-937

A chiral molecular bowl containing three ferrocenes: synthesis and its efficiency in an optical resolution of 1,1′-bi-2-naphthol

B. Ki Hong, I. Su Lee, D. Mok Shin and Y. Keun Chung, Chem. Commun., 2004, 936 DOI: 10.1039/B316520E

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