Issue 9, 2003
From the journal:

Chemical Communications

Coordination polymers based on square planar Co(ii) node and linear spacer: solvent-dependent pseudo-polymorphism and an unprecedented interpenetrating structure containing both 2D and 3D topological isomers†

Dong Mok Shin,a   In Su Lee,b   Young Keun Chung*a  and  Myoung Soo Lahc  

* Corresponding authors

a School of Chemistry, the Center for Molecular Catalysis, College of Natural Sciences, Seoul National University, Seoul 151-747, Korea
E-mail: ykchung@plaza.snu.ac.kr

b Advanced Materials Research Institute, LG Chemical Ltd., Research Park, Taejon, 305-380, Korea

c Department of Applied Chemistry and Chemistry, College of Science and Technology, Han Yang Unversity, Ansan 425-170, Korea

Abstract

Reaction of Co(NCS)2 with 1-methyl-1′-(4-pyridyl)-2-(4-pyrimidyl)ethylene (mppe) in different solvents yields two kinds of novel coordination polymer structures of [Co(mppe)2(NCS)2]n: one of them shows an unprecedented interpenetrating structure with both 2D and 3D topological isomers.

Graphical abstract: Coordination polymers based on square planar Co(ii) node and linear spacer: solvent-dependent pseudo-polymorphism and an unprecedented interpenetrating structure containing both 2D and 3D topological isomers

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Article information

DOI
https://doi.org/10.1039/B210320F
Article type
Communication
Submitted
23 Oct 2002
Accepted
14 Mar 2003
First published
02 Apr 2003

Chem. Commun., 2003, 1036-1037

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Coordination polymers based on square planar Co(II) node and linear spacer: solvent-dependent pseudo-polymorphism and an unprecedented interpenetrating structure containing both 2D and 3D topological isomers

D. Mok Shin, I. Su Lee, Y. Keun Chung and M. Soo Lah, Chem. Commun., 2003, 1036 DOI: 10.1039/B210320F

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